Expert-level engineering thermodynamics covering laws of thermodynamics, thermodynamic cycles, steam power plants, refrigeration, gas dynamics, and combustion.
First law: energy is conserved, delta U = Q minus W for closed system. Second law: entropy of universe increases for irreversible processes. Entropy: ds = dQ_rev over T, measure of irreversibility. Exergy: maximum useful work from system brought to equilibrium with environment.
Rankine cycle: steam power plant, boiler, turbine, condenser, pump. Rankine efficiency: improved by superheat, reheat, and regeneration. Brayton cycle: gas turbine, compressor, combustor, turbine. Brayton efficiency: eta = 1 minus 1 over r_p to the power k-1 over k. Combined cycle: gas turbine exhaust heats steam Rankine, 60% efficiency possible.
Vapor compression: compressor, condenser, expansion valve, evaporator. COP: coefficient of performance, QL over W_net for refrigerator. Heat pump COP: QH over W_net, always greater than refrigerator COP by one. Carnot COP: maximum possible COP for given temperature limits.
Mach number: M = V over speed of sound, speed of sound = sqrt of gamma R T. Isentropic relations: T2 over T1 = P2 over P1 to the k-1 over k power. Normal shock: supersonic to subsonic, sudden pressure rise, entropy increase. Nozzle flow: converging accelerates to M=1 at throat, diverging to supersonic.
| Pitfall | Fix |
|---|---|
| Sign convention errors | Define positive Q in and positive W out at start |
| Using ideal gas for steam | Use steam tables for accurate properties |
| Ignoring pump work in Rankine | Include pump work even though small compared to turbine |
| Adiabatic assumption for non-insulated system | Only apply adiabatic if process is fast or well-insulated |